Faulty Water Pump
If your coolant levels are fine, the next thing to look at is the water pump. This keeps coolant circulating around the engine. If it fails, whether through wear, a belt issue, or a blockage, coolant can't flow, and heat builds up fast.
What to look for: Leaking coolant near the front of the engine, strange whining noises, or overheating at random times. This needs garage attention.